LEICESTERHe hasn't done anything yet. Does he have to reject the foundation year offer before ringing around (Uni's or clearing?), can he ring his second offer (which he still failed to meet the requirements) directly or does he have to go through clearing. For some reason he has his heart set on his first place (Leicester).
Apologies for the questions, I know absolutely nothing about the university system.

(I live there)
He can ring around, doesn't have to reject it as of yet I believe
On UCAS Track he will have a clearing number. On university sites there will be dedicated clearing and adjustment phone numbers he can ring and get an "informal offer" which is an offer but does not have to be accepted yet
Make sure he has his personal statement handy when he does this and also knows a bit about the course he is asking about - will make him seem more enthusiastic to the person on the telephone who is essentially interviewing you