Could be a corrupt boot sector. Try loading up the Recovery console form the Windows XP setup CD and use the commands fixboot and fixmbr. This should fix any bootsector problems and may allow a boot. Before doing this, try running a chkdsk to make sure the drive is ok. Run checkdisk with the following switches:
chkdsk /p /r
And after this has completed successfuly, run the fixboot and fixmbr commands
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