When fitting the brass stand off's inside the case, I think normally there are 9 for an ATX board it is sometimes possible that the motherboard doesn't use all 9 i.e it only requires 8 and the ninth would cause a short on the underside of the board.
If you have the board disconnected try connecting additional fans/hard drives to load the PSU a bit more, usually it needs to see a minimum load before it will switch on.
I see, I will check this in the morning - thanks!