What Crucial RAM are you using? The vanilla stuff or the Ballistix with the Yellow heatspreaders?
If it's the vanilla stuff, then they usually do PC6400/800MHz at 5-5-5-20 without a voltage hike, but the Ballistix stuff runs much tighter timings, even at PC5300/667MHz and it's rated at 2.2V. Aim for PC6400/800MHz 4-4-4-12 if it's Ballistix.
Depending on where the RAM builder bought their PCBs from (I kid you not) some of them will have voltage regulators built-in (I think all newish Corsair does, but don't hold me to that) so you could feed 3V through them and the RAM either just shuts down or disappates the extra voltage as heat - the RAM chips only see what the voltage regulator allows through - usually about 10% over the memory's rated maximum.
2.5V is known to be damaging to Crucial/Micron RAM chips because of a phenomenon called Electron Migration, so you shouldn't ever run Micron RAM over 2.4V if you're smart.
2.2-2.3V is fine though and don't forget Crucial have a very fast lifetime RMA service if they should go wrong.