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E6600 @ 112 degrees

if the temp too high then the Windows OS automatic shut down and reboot itself but it seem it something in your mobo BIOS CPU max temp like my M59SLI-S5 at 60oC that max temp - if it over 60oC then it would shut down itself. Open then case and check the CPU and fan (you may need reapply thermal paste again) and then try again -- 112oC is too hot that would melt the paste too easily.. at my work the IT staff forgot to plug the fan speed pin as the CPU went fried at 110oC and replaced new CPU (its old Intel P2 2.4Ghz) - check your mobo BIOS startup screen

Windows rebooting would be due to instability not anything else. PIV should have throttled and shutdown, dunno what happened there.
 
Pretty sure CPU-Z won't report a CPU throttling, you need to use Throttlewatch or similar to see it happening.

And on the subject of turning it off, it doesn't actually turn it off for thermal emergencies.
 
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