If the pump had failed completely you would know, it probably would last a minute or two at most at idle until the chip overheated.
My older h115i I couldn't feel or hear the pump until link was set to perf mode where it ramped up to a much higher speed. And even then it wasn't overly loud.
What are things like your airflow, rad mounting. Is your rad mounted in the roof with an AIB Ti as that can heat up its intake temps quite a fair bit.
What are the stress temps like at first cold boot?
Well I finally resolved the issue, although I still don't know what caused it. My rad is in the roof and my 1080ti is the Sea Hawk with the fan in the rear. You were correct about knowing if the pump had failed. I removed the power from the pump when in the desktop, and within 3 minutes the temp hit 60c and my pc froze. My pump must have been working after all, perhaps I was just lucky having one that was ultra silent?
My PC still failed to respond so I turned it off, reconnected the power to the pump, and rebooted. The crash must have done something to the registry, as my PC was constantly crashing after that. Sometimes it wouldn't even boot, it would hang before posting. Any XMP profile would crash. Clearing the bios, resetting Cmos, uninstalling/reinstalling the Corsair Link drivers didn't help. I spent a couple of hours diagnosing everything and reseating/testing the ram, my cpu, my ssd's and I unplugging everything. Nothing made a difference.
Enough was enough, I formatted Windows.......and low and behold, everything was perfect from there on. When I eventually came to testing my delidded i7 8700k it was a completely different story this time round, my OC now had lower temps. This enabled me to drop the voltage bit by bit from 1.35v to 1.27v. Even now, I am still testing and dropping my volts. I am so far getting a stable overclock using Realbench and Prime95. My max temps now are 65c which is great.
Who knows where my final stable OC will end up. Maybe I can start jumping from 5.0 to 5.1/5.2. Thanks for all the advice guys. It looks like my chip and cooling are now doing okay