The dual receiver doesn't do low voltage switching so be careful what you connect it to in your boiler as it could damage it.
Looking at your boiler manual you'd run a cable from pin 4 on the hive to the mains thermostat terminal block on the boiler and from there back to pin 2. Make sure you remove the bridge wire on the low voltage terminal block also.
Looking at your boiler manual you'd run a cable from pin 4 on the hive to the mains thermostat terminal block on the boiler and from there back to pin 2. Make sure you remove the bridge wire on the low voltage terminal block also.