£20 a wheel without tyres and if you leave them with them for a few days. £30 a wheel if they come in with tyres. £40 a wheel if you want them the same day (£45 a wheel if you drop the wheels off on the car), which is quite possible when you're a 3.5hr drive from B'ham. Adds up pretty quickly and you're no longer at £80, but easily double it. Plus return fuel (two lots off if not same day).
I've been thinking about getting mine done by City Wheels, and I'm only 2hr from B'ham outside rush hour. The problem is I'd need the same-day option as it will cost £50 in fuel, so that's £210... Not quite £80 is it! If I leave them with them it's £170, still very much not £80. That's all assuming I can get a spare set of wheels too, cos if I can't it's £230.
Now, Acme is roughly twice as a far away, and he gets even worse fuel economy than me in his S60, but even conservatively let us say it will cost him £100 in fuel. If he goes same day, leaving at 0430 to get there for the 0800 drop off time, before collecting them at 1700 and finally getting home for somewhere around 2030, it's going to have cost him £260 in fuel + refurb cost, plus having to get lunch/dinner in Birmingham/on the road. That will put him, again conservatively, at £300 for getting 4 wheels refurbed on a £250 car, and will have wasted an entire day with 8 hours driving and 9 hours of fannying around in a frankly rubbish city. If he can't do the same day then add another £100 in fuel.
Yes, powder coating is the best option for finish and longevity but is it the best option in this scenario, for a car worth £250? Absolutely not. Perhaps we can focus on answering the question he asked now.