Well you need to know the height of the room as well. Or do as above just use a thermometer.
If you really want to work it out then you can do a calculation to work out it out exactly, using the specific heat capacity of air (fixed pressure though) ~1.006 kJ/kgC, and then you need the mass of the air density at 15c, so ~1.225 kg/m^3, then do your density x volume calculation, and use that to work out the energy needed which is 1.006 x (density/volume) x5, the 5 being the differential you want to calculate. You've get you answer in kJ, so if it was a 5x3x2 room 30m^3 then it would be 1.006 x 30 x 5.
You then need to work out the output of the radiator.
If you're just checking the rads are big enough then it isn't that complicated.
Find a heat loss calculator online, City Plumbing have a good one, put in your room sizes, construction, window area etc and it'll give you a btu and Kw figure that your rad should meet.
Little trickier finding the exact output of the rads as each manufacturer will have slightly different ways to work it out but find the same size rad on Screwfix or somewhere and the figures they give will be close enough.
As the op is finding out though, trvs aren't great at giving or maintaining accurate temps.