people run in the 90s but i wouldn't have it in NORMAL usage over 75C, i think TJmax is 100C so theoretically anything up to that, but i wouldn't recommend it for any length of time.
you have to remember there's nothing that will push your I7 as far as the stress tests people run, for max temp your CPU will get to try IBT/LINPACK.
If under normal usage you are getting max high temps above 75C i would either take it down a notch or get some new cooling.
64c is fine for 3.2ghz
i've got the same rig as you, and 4ghz i idle at 40-45c and max out 80-82c
I've been running this setup for over a year and it's perfectly fine.
You always want lower temps, but the i7's do run hot.
Like Sayso said, these are bench tests, in normal conditions, the highest temps i've seen whilst running a game or encoding a video is around 70-75c. And that was during the summer, so go ahead and squeeze more out of the 920.
Just don't too nuts on the volts