I have this in my router settings, will it be any use to me?
Can I ask which model of router that is?
6to4 is an automatic tunnelling protocol, it allows IPv6 packets to be encapsulated in IPv4. I suspect your router is allowing 6to4 in an anycast relay configuration, which simplifies configuration.
If your router gets a public IPv4 address, it can use this to generate a IPv6 prefix for you. This takes the 6to4 prefix 2002::/16 and concatenates the IPv4 address (in hex) to it.
So for the IP address 82.163.123.1 it produces the Prefix
2002:52A3:7B01::/48 (this becomes the IPv6 network for your site)
Your router will use this prefix for your internal network, taking one of the /64s that this prefix covers, possibly the first one (2002:52A3:7B01:0::/64) and advertising this into your LAN. Devices on the LAN will use this prefix to automatically generate their global IPv6 address(es) and can use this to talk to other IPv6 addresses.
IPv6 traffic from these nodes can go to the router which will then encapsulate it in IPv4, and send it to a 6to4 Relay (using the anycast address 192.88.99.1 as the destination). The 6to4 relay is dual-stack, having access to both the IPv6 Internet and the IPv4 internet.
Once the encapsulated packet arrives at the relay, it removes the encapsulated IPv6 packet, and sends it natively over the IPv6 internet to the destination. Return traffic is similar, being routed to a 6to4 relay, and then encapsulated in IPv4. The 6to4 relay discovers the ipv4 endpoint (your router) by looking at the ipv4 address encoded in your prefix.
The usefulness of 6to4 is limited; the reliance on relays means that it is less reliable and robust than IPv4. Because of this all the major operating systems now prefer IPv4 over 6to4 based IPv6, so it should only be used when there no native IPv6 connectivity, and no IPv4 connectivity to the target. It is possible to make it more preferred than IPv4, but you may notice more brokenness.
NAT-PT was deprecated as there were a lot of operational problems. It will depend on your router as to how it is implemented and what it is capable of doing.