I notice there are also stocks and shares ISA's, I assume these carry considerably more risk?
The ISA itself doesn't have a particular 'risk level' as it's just a tax-free wrapper for investments in shares. That said, any stock market investment will carry greater risk than just leaving cash on deposit (and potentially provide higher rewards).
Shares are a medium- or long-term investment. You shouldn't really think about it unless you're willing to lock the money away for at least 5 years, and preferably 10 or more.