Cheers guys, I just assumed (wrongly lol) that I'd need to cool the 'hot' water coming from the GPU before it gets to the CPU. But i supoose once the system is up to temperature, the water will be pretty much the same temperature anywhere in the loop?
@Ash2097 I initially tried it the rad the way you suggest, but as i only have straight barbs, there's no clearance between the rad and PSU. When i get a CPU bloc, I'm going to route the tubing neatly, plus buy compression fittings, so i may be able to swap the rad round then!