Thanks for all the replies guys. I can't get the neighbour to try jump starting me again. I rejoined Start Rescue yesterday and I can use them 24 hours after joining which is 3.40pm this afternoon. They'll no doubt bring a heavy duty jump starter to get me going.
When I joined I was asked if there were any faults and I said no. Do you think I can call them today after 3.40pm without it looking suspicious or should I wait until tomorrow?
If the T&Cs state 24hrs then you've complied with them.