Well, the question is can anyone tell the difference between them? I believe silver and copper are both fine for producing cables up to the job, so as long as they are both of sufficient design (16AWG seems acceptable for copper, not sure about silver), I can't see why anyone would be able to tell the difference. But If someone wants to prove me wrong they are welcome. Again, it's not about being sounding the same by scientific
theory, it's about whether they sound the same based upon scientific
evidence.
I don't get why anyone uses any kind of fancy speaker plugs, if you're that concerned why not just go bare?
Anyway, on the subject of tests, a few ideas (this is a bit of a brain dump):
Pick 2 cables A & B that you want to check the difference of (I'd propose one that should theoretically do the job, and another a lot more expensive that should theoretically be neutral - i.e. doesn't have anything sneaky in there to intentionally alter the signal). You'll need a fair few trials, so you don't want to be trying too many cables as it will take forever.
Pick another cable, C which shouldn't be up to the job, some awful bellwire or similar.
Start with an initial trial, comparing cable C to one of cable A or B.
Analyse results. If you have enough trials you might at this point split out anyone who was unable to spot cable C (although this can get v dodgy when you go down this road). Of course it nobody was able, stop at this point as there's not much point carrying on!
Next, move to trial 2, comparing cable A to B.
Now, the big problems are, even after disguising the cables, you'll still have expectation bias. One way around this of course would be for someone else to swap around the cables independent of the listeners, but then you have the problem of them interfering with the experiment. One other way around could be to use duplicates of A and B and asking for the listeners to match up A to C or D etc. and let the listeners switch back and forth at will. I expect this could lead to problems with trial size though and it could end up taking hours.
You would have course have to pre-define number of trials and publish all the data as well. If you're only doing enough trials to analyse across the whole group don't start doing subgroup analysis - it's just cherry picking!