Replace every capacitor related to Vcore, bridge, AGP, anything that draws any significant current. It works out to about 20 caps IIRC. AsRock uses some (5?) Panasonic FJ's for Vcore but the rest are not good capacitors, i just swapped the lot.
Added some tants and ceramics to the vacant pads around the CPU and MCH too.
Dont use the on board VDIMM regulation, i replaced VDIMM with a homemade linear regulator. I think i was feeding it about ~3.2-3.4v
Put the control of VID onto dipswitches, gives you upto 1.6v IIRC. The Vcore regulator AsRock used is pretty good. If you need more than 1.6v then you'll have to cut the Vcore feedback trace and put it into a potentiometer (maybe 100 Ohms) should allow precise adjustment over VID values the controller accepts.
If you wanted to PLL modify the 775i65G that might get you into the 350MHz region on a Conroe, but thats it realy.
I dont have a 4Core-DualVSTA, but i think you'll be lucky to get toawards 400MHz on a heavilly modified board. There's some registers on that chipset which give much nicely performance IIRC, use WPCREDIT maybe, would "help" if you could get the chipset datasheet too
