Galvanic corrosion only occurs with dissimilar metals in
direct contact and in the presences of a electrolyte.
No contact, no GC - note if you have metal fragments/filings in your loop this will give you GC issues especially if they get stuck in a copper block matrix. But they will only affect the aluminium increasing the life span of your copper block.
Normal corrosion (rust to you and me)
It happens - with aluminium in a non abrasive area it's a good thing as the 'passivation' of the metal acts as a shield to further corrosion (anodising aluminium is taking this one step further and then 'sealing' the surface with a different compound - Teflon for example)
Stopping it
Coating the metal - Plating, painting or enamel - in WC’ing terms always with plating - done by most of the aluminium block manufactures usually with zinc sometimes gold.
Using corrosion inhibitors - (antifreeze, G200 etc) These form an electrically insulating and/or chemically impermeable coating on exposed metal surfaces, to suppress electrochemical reactions (hard water can do this btw but calcium deposits are not flow rate friendly) And deionised water goes one step further by significantly reducing the ability for the coolant to be a electrolyte.
I use a Res2 with four copper blocks – not had a problem with corrosion.
Due to the Zalman’s flow rate Algae with be a bigger issued – again the G200 or nuke will solve this
Edit:
im not sure whether i want to get this external one kit or get an internet kit. Whats the advantages?
Do you mean passive external watercooling and active internal WC’ing?
Not seen an internal passive WC’ing system as the inside of a pc has a higher ambient temp. The hybrid Res XT and can be installed internally but it uses fans.