The 5.1 install is a pain if you are using full blown SQL. If you are using SQL express its next next next!! Although its only advised for 5 hosts and 50 vm's. I found a great guide for the full blown SQL install with screenshots for every step. I'll dig it out if you need it.
/edit dug out and here it is:
http://www.vkernel.ro/blog/installing-vmware-vcenter-5-1-on-windows-server-2008-r2
/edit dug out and here it is:
http://www.vkernel.ro/blog/installing-vmware-vcenter-5-1-on-windows-server-2008-r2
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