Old AS5

If it was me l would buy some new thermal compound, but if you stored it away from the sun and in a cool place l dare say it is ok.
 
if it's still easy to spread then it's fine to use - it only really goes off if air gets in to it or it heats and cools (e.g. if you left it in the sun so it had repeated heating and cooling)
 
Squeeze some out onto something and have a look at it, this will also clear the dried up crap in the nozzle out and present fresher stuff from within the tube?
 
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