Don't worry about the computer failing to boot - it's part and parcel of overclocking. Same with bluescreens and reboots when stress-testing. Simply put, it's not possible to find out how far you can go unless you go "too far" and back off.
Let's tackle the problem step-by-step:
* First - load the BIOS defaults and reboot to make sure they're set.
* Second - set the CPU VCORE ("main CPU voltage") to 1.200v, and set your CPU multiplier to 42x. Find the "uncore ratio" and set it to 41x (keeping the uncore one or two multipliers below the CPU multiplier is a good idea).
* Third: Boot into Windows. Hopefully it will go just fine in at these settings. Download
Prime95 ,
CPU-Z, and
http://www.techpowerup.com/realtemp/. Open all three up.
Now, run Prime95, while keeping an eye on your temperatures in realtemp. In Prime95 choose "Small FFTs", and leave everything else at default. Let it run for 10-20 minutes - if it doesn't fail, or lock up Windows etc, then that's a good sign that the CPU is stable at these settings. Watch your temperatures though - if they go above (say) 85-90C then you should stop the test and choose a lower CPU voltage. If all is well, then increase the CPU multiplier and uncore ratio by 1 and try again until you get a failure in Prime95.
Note - the above assumes you have a half-decent aftermarket CPU cooler. If you're using the stock intel cooler then I would set a lower CPU voltage to start with (say 1.15v) and start with a 41x multiplier. Then buy a decent cooler
Report back how the above goes, and we can see where to go from there. Also post your exact specs - what CPU (4770k or 4670k), motherboard, and RAM.
Good luck
