Thanks for the replies guys. Yeah, it gets very hot when loaded, in fact I would almost say it's one of the hottest components to touch in my system.
It does not seem to be the exhaust air from it that is hot either, if you touch the back of the PSU it is really hot, yet there is no great amount of hot air being exhausted, although the Tagan PSU fans don't spin at any great rate either. Maybe that's half of the problem, it is not pushing enough air away?
I also don't think the PSU is expelling much, if any of the heat from the CPU, as it is the type with an intake at the front and exhaust at the rear. There is no fan on the side of my PSU.
As for the airflow in the case, it's pretty good really. My case is a Jeantech Phong, which is actually pretty decent for the price. I have a 120mm Akasa Amber at the lower front blowing in over my 3 HDD's, a Scythe Kama Bay up top blowing in towards the CPU, a Antec Spot Cool blowing air into and over the 8800, a 80mm Asasa Amber on the case side drawing heat out, a Thermaltake Cyclo PCI Fan drawing the heat away from the rear of the 8800, The ACF7, then a 120mm Akasa Amber exhausting the CPU heat, almost directly behind the AC7F, on the rear of the case.
I also have a spare Antec Spot Cool, maybe I will install that and direct it at the PSU intake in the case and try to force more cool air through it. Would that help?
Also, if I open the case up, temps actually rise by a degree or 2, so the airflow is serving it's purpose from what I can make out.