I would be very surprised if the powerline themselves are syncing even close to 100mb. Most times I see ~50mb odd on average.
Which powerlines are they? Depending on the brand they sometimes come with an app that can tell you the speed between each powerline node. If not, just do a test large file transfer between PCs.
EDIT: For TP-Link, this should be it:
https://www.tp-link.com/uk/support/faq/1086/