240GB RAID 0 SSDs + rsync/robocopy to 640GB.
Set up your SSD raid 0, install OS. Clone 240GB volume to WD 640GB.
Set up rsync/robocopy cron/scheduled task to keep both sides sync'd.
If your RAID fails you should have a bootable copy on the 640GB.
It's not RAID, but it'll do what you want it to more or less. How up to date the "mirror" is depends on how often you run the rsync/robocopy cron/scheduled task.
As a side note, I'd partition your WD 640GB into a 240GB + 400GB volume. 240GB for the SSD "mirror" plus 400GB storage or whatever.