In terms of RAID0 benefits, you will get a lot faster read times from your drives due to 2+ of them working together. In a real world example it would speed up loading in games by a reasonable margin (but see below). But with RAID0 as mentioned, if one drive fails then the other fails with it. It won't increase FPS at all however, it just makes accessing data a lot faster than it would have been normally. An example could be that say one of your drives has about 65 MB/s reading speed on average, now if you took another duplicate drive, turned it into a RAID0 array then you would probably be looking at around 110-120MB/s average reading speed.
In regards to loading times in games, it will depend however if the game requires data to be uncompressed before it's used. Games that don't require decrompressing of data will speed up, but when you start adding decrompression of game data into the mix, then you are moving onto write speeds and also more emphasis onto your CPU speed. Whilst you would still see an improvement, you would see more of an improvement in games with pre-decompressed data. Your write speeds are increased with a striping (RAID0) and tend to get better depending on the stripe size used.