The good side of the ssd caching solutions, revo hybrid, intel srt is two fold:
1) They do all the boring coping to and from HD for you
2) They cache what you actually use so they do not waste costly ssd space storing miscellaneous junk. Example, I'd guess 80% of a win7 install is misc. junk that will never/seldom be loaded?
The bad side is potential wear on the ssd as data is added/removed from the cache: The intel recommended implementation uses SLC flash, revo hybrid is overprovisioned by 28%. Interestingly, the new OCZ standalone Synapse flash/cache drive is overprovisioned by 50%!!
How does the wear issue affect you? I have no idea. Your usage patterns, the page erase life of the drive and the caching algorithm and write options will all come into play.
Finally, do you need >500MB/s? Indeed, do you
need >150MB/s?
To test this for my own amusement I've been playing with FancyCache and SuperCache using 2x HDD Raid0 and 4GB RAM for the cache area. Oh boy you should see the benchmarks fly, but loading apps and compiling code shows little improvement. Watching the numbers and graphs change on second and third test runs suggests the inbuilt windows caching is doing its job and takes precedence over these 3rd party programs. Delaying writes can speed some things up, notably writing

, in that it allows the system to get on with things instead of waiting for all bytes to hit storage, this could be of benefit.
I've used Raid 0 for years now, and in that time I've had hundreds say 'you'll never notice the difference in real use'. They are of course wrong, you do get a more snappy feel the first time something loads and if you are endlessly rebuilding multi GB databases the speed difference really shows. These days I'm becoming more convinced that outside of benchmarks and 2 system boots a day, my money is better spent on RAM and allowing windows to take care of itself?
Still, I'm awaiting the hybrid benchmarks with much anticipation: just how slow is that little HDD? can the HDD be changed? Can I make 2 run in Raid0, lol, or should I go back to my dreams of a sexy LSI 9260 + 4x HDD Raid5 + 4x SSD Raid 0 Cache? Even bigger lol!
OCZ RevoDrive Hybrid (user manual):
http://www.ocztechnology.com/ocz-revodrive-hybrid-pci-express-storage-solution.html
OCZ Synapse Cache:
http://www.ocztechnology.com/ocz-synapse-cache-sata-iii-2-5-ssd.html