Most of a bomb's filling is secondary explosive, ie a sensitive explosive mixed with an inert compound to make the explosive easier to handle. So it needs a detonator (primary explosive) to set the main filling off. You can drop a bomb without a fuse and it won't explode as it's that insensitive.
Now add a chunk of time and temperature variations, and the sensitive explosive starts to separate from the inert compound. You can get crystals forming round the cap covering the fuse pockets where the sensitive explosive is leeching out. Do not try and unscrew the cap.
It's been an issue since the beginning. The first high explosive was nitroglycerine...that spelling looks wrong...hmm...apparently it's right...which was very useful for mining and construction work but unreasonably dangerous to make, store, transport or use because it's too sensitive to various things including movement, vibration, trivial impacts...all manner of things. I vaguely recall an advert many years ago for a luxury car brand that showed a container with a tiny quantity of nitroglycerine attached to the top of the dashboard while the car was being driven on a smooth road. Proof positive that there was no vibration in the dashboard. Very striking to anyone who knows anything about nitroglycerine, so it was probably completely useless as an advert. The overlap between people who were in the market for a luxury car some decades ago and people who know anything about nitroglycerine must be very small indeed.
Anyway...I'm wandering off topic because I've drank half a bottle of beer not long after taking some codeine. Not a great plan. My head's in the shed. The pain's gone away though, which is nice.
So...yeah...explody stuff. Alfred (I think) Nobel was concerned about people being killed in accidents with nitroglycerine, so he set out to make it safer somehow and came up with the idea of mixing it (nitroglycerine is a liquid, so mixing it with other stuff is relatively simple) with an inert compound to make it much harder to detonate. Sawdust and powdered clay or some sort of dirt IIRC. It worked. He called it dynamite. He wasn't at all pleased by the fact that people promptly weaponised it. Which indirectly led to the establishment of the Nobel Prize - he had (unfairly IMO) become associated with explosive weapons and he didn't want that as his legacy.
Wandering back to the point...the issue you refer to applied right from the start, from dynamite. Over time and depending on environmental conditions, the nitroglycerine seperates from the inert compound. "sweating", it's called. Then it might explode if you touch it, step near it, bump into whatever it's stored on or in. Maybe if you sneeze near it. If dynamite looks wet, it's time to walk very softly away.
Some scientists created the most unstable explosive they could imagine, apparently out of curiosity. "Hey, this molecular structure would be ludicrously unstable...I wonder if we could make it?". So...azidoazideazide. All the nitrogen atoms in all the wrong bonds. Despite having the best experts and the best equipment for this sort of thing, they were unable to determine how sensitive it was because it was too sensitive to measure how sensitive it is. They were unable to build anything that would impact it with a small enough force to not set it off. A tiny probe moving at half a millimetre per hour? BANG! Dim light? BANG! Sometimes it exploded for no reason that anyone could determine. In a lead box on a shockproof table underground in absolute darkness in a controlled environment.
EDIT: I vaguely remembered an entertaining article from a chemist and was able to find it again:
https://corante.com/things-i-wont-work-with/things-i-wont-work-with-azidoazide-azides-more-or-less/