Changing the wheel alignment involves adjusting the suspension geometery, so they are one and the same. Cost me about £65 to get my Mondeo done last year, but it made a real difference to the feel of the car and everyone who drives it comments how straight it tracks at speed.
Before and after settings on my car (PDF)
As you can see it was the left rear that had too much toe in, and the total toe on both rear wheels was well out. This was needing a touch of steering to the left to correct it all the time which scrubbed the inside edge of the right front. It shows the reason why a normal tracking is often of new use - the front track was pretty much level (its shown in red because I asked them to use the ST220 settings which set the front wheels exactly parallel, the ST TDCi wasn't on their system but normally runs a little more toe in on the front than the ST220).
That was done using a Hunter DSP600 setup - they put the car on a scissor lift with turnplates so they can turn the steering wheel with it on the ramp. They attached targets to each of the wheels which reflect a laser beam and took a reading, then they bounced the car a bit and ran through moving the steering lock to lock a few times and took the final before reading. They then made the adjustments which appear on the screen in real time so the fitter can see what effect its having. Once its all OK they do a printout like the one i've attached.
It sounds like you have too much toe out somewhere to scrub the outsude edges, but your tyre size won't help with big sidewalls givng a lot of flex if you throw the car around a lot, but these laser alignment machines will show you exactly what the wheels are doing.
If you're getting new tyres you want the alignment set with the new tyres on, preferably as soon as possible after they are fitted.