They considered only the lithium-6 isotope in the lithium-deuteride secondary to be reactive; the lithium-7 isotope, accounting for 60% of the lithium content, was assumed to be inert. ... However, when lithium-7 is bombarded with energetic neutrons with an energy greater than 2.47 MeV, rather than simply absorbing a neutron, it undergoes nuclear fission into an alpha particle, a tritium nucleus, and another neutron. As a result, much more tritium was produced than expected, the extra tritium fusing with deuterium and producing an extra neutron. The extra neutron produced by fusion and the extra neutron released directly by lithium-7 decay produced a much larger neutron flux.
The result was greatly increased fissioning of the uranium tamper and increased yield.
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