ATI don't have digital vibrance, that said they do have gamma/colour controls, and a lot of people used to believe that the colour was richer on ATI cards anyway, in a sense they didn't need digital vibrance. Last I heard this being an issue was back in the series 7 cards though, as NV/ATI have both made improvements, and are now running 10bit, ATI were meant to be in the lead with this etc.
RE: Physx, there are rumours they will eventually support it, they are also going with the now Intel owned Havok Physics, and ofc OpenCL over CUDA, so who knows where that will end.
Performance wise, when you consider the price to performance with NV, or the 1GHz stock cards for 4890s, they're pretty even, and just cater to difference price points in different ways. The 1Ghz 4890s are showing as faster than a GTX285 in a large percentage of games.
Games profiles can be done however I'll admit they're not quite as simple as NV, you basically have an option in the CCC to make profiles, these can be triggered to change by clicking a desktop icon, right clicking the CCC icon in the taskbar, button combo presses etc, when they're run they can also open a programme. So to get NV style settings what you do is make a profile for the game, save it as such with an appropriate name, link this profile to the exe/shortcut you want to run, and then open the game by either the new ATI profile desktop shortcut or by the CCC icon in taskbar. Not perfect, but it does work.