Shouldn't be much slower... won't really be that much quicker either... windows boot is minimal on an SSD really... where the hard drive comes into the equation.
Motherboards have a greater effect on the boot time.
It could be possible that the motherboard that review have used is a bit slower at picking up the pci-e bridge used for these.
Like if you were to enable raid-0 on two normal SSDs through your onboard raid or pci card... the boot time will actually be slower by a good 5-10 seconds because the post process will have to initialise the raid controller and give you time to be able to select the raid controller configuration.
With Asus X99-S and Samsung SB951 (M2 4x PCI-E)... the boot time is not noticeably different from 256GB Samsung 830 & quicker than when I have 2x 480GH Intel 730 drives in Raid-0.
Whats your boot time with your Intel 750 series?
Here's an image from the techspot review I'm referring to:
I'm in the market for a good PCI-E ssd, thought the Intel may be the one for me, though I'm waiting for the Samsung M.2 NVME drive, since it has way better boot times than the Intel 750.