It wont cause issues, but its more the case of the only fuel sold in this country is above what's needed so if its possible to "water down" the mix that would be great, the point is simple saving money by not paying extra for nothing, I would imagine if the was a simple cheap way of downgrading the fuel it might even cover the cost of road tax.
It doesn't work like that, higher RON fuel isn't a stronger mix that can be diluted with adding some base liquid.
If he can get the engine tuned for 95 ron he may be able to get more mpg out of it, that would be his best bet.