Can't remember what cooler you have but don't try this if using the stock cooler. Here's mine for 4.4Ghz. Got settings for 4.5Ghz too. Your bios should be similar to mine.
CPU Core Ratio - Sync all cores
Ratio Limit - 44x (45x for 4.5Ghz)
*Min CPU Cache Ratio - 8x
*Max CPU Cache Ratio - 44x (you may want to leave these until stable and then play around with the cache)
CPU Core Voltage override - 1.265v (1.285v for 4.5Ghz) (use manual voltage until you find the max overclock and then we can work out the offset).
CPU Cache Voltage - Manual Mode
CPU Cache Voltage Override - 1.300v (leave at stock until clocking the cache)
CPU Input Voltage - 1.90v (4.4Ghz or over and mine won't boot with less)
I have given you the settings for the ram in your motherboard thread. You may have to tweak things a little to suit your setup. Keep a eye on temps and don't use Prime, Aida or anything that uses AVX instructions for stress testing. I Use IBT V2.2 but some say that it uses AVX. I don't think it does as it doesn't force the extra 0.1v that the likes of prime, Aida and linx does plus the temps are much lower. Alternatively use Asus Real Bench.
I have loads of other settings as well but get stable first. I have found lots of tweaks to lower power usage at idle as well. I am down to 61w total system power while idle/browsing the internet. Again though, get your overclock stable first.