I've just fully rebuilt the system over the weekend, including stripping off every heatsink on the board and applying AS5. I've relaid the BigT with AS5 again, tested on the bench, I was right in thinking that the bracket underneath the board get hots :/
I've modded the case as well to improve the air flow from intake to exhaust. I'm even tempted to get a duct for the BigT from the side window - it does have an 80mm fan in it already ... hrmm.
Anyways, after extensive cable tidying I've also managed to squeeze another 120mm fan into the case to help direct air flow over the CPU/Northbridge and VR Heatsink as well.
I've not had chance to test this yet, probably another 2 days or so, but I'll keep the thread updated.
I did manage to switch it on this morning to check some BIOS settings, and the CPU Idle temp in BIOS was hovering around the 45C mark. I'm hoping after the AS5 settles down across the board I'll see a marked improvement in temperatures.