Unraid won't allow you to add a disk without pre-clearing it, that pre-clear on a 3TB drive will take a lot longer than a few hours at single pass and you'd normally do multiples (3 minimum). All data will be lost, every sector written to and then re-read and verified. You can add one disk, copy data to it, then pre-clear the other disk and add that. When you ad the second drive it'll be as a parity drive if you want to have any backup, so i'd suggest you add in this order with the caveat that you have no protection till you are done.
1. Pre-clear a 3TB RED.
2. Install Unraid with the drive you cleared in step 1.
3. Copy data from 2TB to Unraid.
4. Pre-clear 2TB drive.
5. Add 2TB to unraid drive pool.
6. Copy data from other 3TB to pool.
7. Pre-clear remaining 3TB RED.
8. Add drive cleared in 7 to unraid as a parity.
You will now have 3 drives with 5TB of parity protected pool. An SSD cache drive is advisable if you plan on running a lot of IO heavy things like sonarr/radarr/NZBGet/Plex etc as you don't want to run that on the pool, same with VM's.
This assumes you have enough space to do this and it will not be a quick process.
A simple/cheap option would be GSuite with unlimited storage for a few quid each month and just use that if your connection is fast enough, it's perfect for media storage. If you want a nice simple way of doing it you have two unraid plugins that will allow rclone to mount GSuite and another to expose it to dockers etc., or use PlexGuide as a VM, I know people spending circa €15 a month with automated downloads, unlimited storage and adding 20TB/month of content, you can do it for about £8 a month if you run local rather than using a VPS.