The reason that I want to do this is that backing up data is difficult and expensive- in order to do so you always need an equivalent quantity of backup storage space to that which you actually make use of routinely. So in order to expand a 4tb nas drive, i need an additional 4tb for backup purposes, as well as the capacity i would be adding through new drives to the array. Given that some of the disks in the array are already being used for data redundancy, this represents a painful waste of capacity.
I'm tempted to ditch raid entirely and just keep all my disks seperate with data evenly distributed across them; that way a disk failure, whilst an irritation, is still only a portion of my overall media library, and I get to keep all the capacity of my disks. In any case, this kind of data isn't vital, it's just a pain to restore when lost.