I have a 3700X with PBO Enabled and PPT limits etc increased, running under a H100I pro, max temps in Cinebench 2.0 Multi test is 75c and scores just over 4700 points, single core score of 509 and in The Division 2 i see around 59-61c max temp, my pump runs on Extreme during games and benchmarks but fans on a custom curve, max water temps ive seen are 42c after a lot hours of gaming.
With an all core clock set to 4300 and volts set to 1.3v i got max 60c in the same Cinebench 2.0 test and score just over 4950 points, single core dropped to 478 though.