is she into shooters? try half life 2, great story on it, gets ya more used to the aiming and pressing wsad etc for then playing counterstrike:source? then portal bit more advanced once used to the engine and physics? 
also, sims 3 is great i was hooked on it for a few weeks, could spend years on that thing so i got it out of my system lol

to the skyrim comments ^
i used to play morrowind on xbox which is a pad obviously back in the day befor the 360, then i moved to pc gaming.
and due to playing fps shooters for years, and still to this day (battlefield 3 awsome!)
i find WSAD configuration good for any game, car games (track mania), LFS racing simulator (i use W=Gas S=brake A=down shift D=up shift and mouse steering left and right), oblivion then skyrim (easyer to aim bows due to playing shooters for years), any game that doesnt really use these buttons i set it up to use them.
	
		
			
		
		
	
				
			also, sims 3 is great i was hooked on it for a few weeks, could spend years on that thing so i got it out of my system lol

to the skyrim comments ^
i used to play morrowind on xbox which is a pad obviously back in the day befor the 360, then i moved to pc gaming.
and due to playing fps shooters for years, and still to this day (battlefield 3 awsome!)
i find WSAD configuration good for any game, car games (track mania), LFS racing simulator (i use W=Gas S=brake A=down shift D=up shift and mouse steering left and right), oblivion then skyrim (easyer to aim bows due to playing shooters for years), any game that doesnt really use these buttons i set it up to use them.
			
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		 thats a bit of a steep learning curve but definitely no better way to learn how to play an fps with keyboard + mouse.
 thats a bit of a steep learning curve but definitely no better way to learn how to play an fps with keyboard + mouse.