Loop order really doesn't matter.
a 280mm rad cannot cool such a heat load, unless you run 100% fan speed but that is simply too loud, you want to exaust that kind of heat out of the case but in the op's case i reckon the 480mm rad is dumping all that heat back into the case, because the 280mm rad is trying to cool down it cant take anymore heat away from inside the case and a 120mm exaust isnt enough, the loop will continue to heat up until it reaches a max, 90c on cpu and 70c on gpu is far to high, my old 5950x never got past 70c even under bechmaking or games and my gpu was in the mid 40's (6900xtu liqid devil) but i run dual corsair x2 420mm radiators and a d5 pump, even my new 7950x setup runs cool.
this is my watercooling setup 420mm rad top taking all the heat out and a front 420mm cooling the water down with minimal heat going back into the case (corsair 7000d) and a d5 pump/res
fans at idle are around 840rpm on all 7 and get under load hit around 1300rpm. Pump rpm idle around 2700rpm and under load hits around 3900-4100rpm
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