Nope. The PWM headers are complete red herrings. They're not to do with PWM fans or pumps at all and are (if my failing memory works properly) a different voltage entirely. I think they're for lighting.
Best way is to ditch the molex and stick all four wires into a 4-pin fan plug connected to an Aquaero fan header. The 6 has the power to run high-power pumps directly (30W per channel or 36 with heatsink) and it makes the wiring neater with just one cable...especially if you sleeve it.
Thanks bud, sort of annoying because I've got 17 fans to connect also and those are via 3 Splittys... leaving me one spare, unless the control would work bi-wired if you leave out one of the RPM connections? Or maybe the splitty would manage it but I doubt it... guess I could run one off the mobo header and one on the Aquaero.
They are indeed sleeved, probably need to redo them though to the correct colour.