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From the Sunshine soundtrack.
I always turn the volume right up for that part of the film.
Some of my favourites:
Last of the Mohicans, the part at the beginning when they are chasing the deer and at the very end, the battle on the moutainside.
The Mission, the music on the river
Lord of the Rings, all of it
Star Wars, all of it but particularly themes like Yoda's and Leia's themes.
Basically anything by John Williams.
Pirates of the Caribbean, the music from the first film, Davy Jone's theme from the second and the music as Jack is eaten by the Kraken.
Gladiator, particularly "Now We Are Free" at the end and the battle music at the beginning
Serenity, the opening theme and the "wonky" piano music throughout for River
Cinema Paradiso, the main themes
Some of Ennio Morricone's work from the Westerns
The music from Star Trek II The Wrath of Khan, particularly the part where the Reliant is closing in on the Enterprise
All I can think of off the top of my head.