The pics are on the way but at the moment I'm downloading the drivers for my soundcard.
I'll confess, the reason the pc wouldn't power up was that I'd managed to insert the wrong connector into the 8 pin power connector!! Everything else was connected correctly but I imagine the psu wouldn't turn on due to some safety feature.
So today I'm installing drivers and programmes after spending the last couple of hours re-routing my cables.
Main points I've learnt which may help someone else who's got very little experience of computer hardware and has never put together a pc before:
1. Plan your build - read everything you can on how to install a motherboard, psu etc. Don't rely on the first article you read - there are lots of different types of components and so your particular set may be different even if only in a subtle fashion. Also don't rely on the manuals that come with the components - absolutely hopeless, although the on-line ones are better.
2. Take your time
3. Some cases come with standoffs pre-installed, that are not brass and some are even rivetted to the case and can't be removed!
4. Read the motherboard manaul carefully before attaching different devices to the motherboard - it is possible to install devices incorrectly even if they fit - you need to check the polarity diagrams in the manual.
5. When connecting the power cables, remember that most devices have to have external power (including sound cards). Even though the experts will say the power cables can only fit one way and can't be fitted incorrectly, it is possible to do this, so be carefull. You can also fit the power cables behind the back of the motherboard and outside of the main compartment. They fit between the case panel and the back of the motherboard, which will help with cable management.
6. If the pc doesn't power up you can check the psu by disconnecting everything, except one case fan, and shorting the green connector and one of the blacks on the 24 pin main power connector - if the psu is ok the fan should spin. The psu needs to have something connected like a fan as it needs some load to operate.
7. Be careful when installing everything in the case as its easy to cut your hands without realising and end up bleeding over your expensive processor, case etc
8. Use isoproppyl alcohol to clean thermal paste off a psu with a lint free cloth. Not nail varnish remover, or saliva, as someone on the web suggested!
9. Some aftermarket coolers don't fit some motherboards without covering some of the RAM slots, meaning a loss of RAM capacity - check carefully.
10. Overclocker forum members are happy to help (and laugh at you occasionally

) if you ask for help with your build and post lots of pics.
Cheers