As some people have said, it might be better you use a bootable liveCD before you do anything drastic, theres one with a miniXP copy on but I cant really name it for obvious reasons (not entirely legal because of the programmes on it), many linux discs should be fine but wont be as easy for you to use.
Boot from the live CD, and copy your files onto a USB drive before you do anything else.
That way at least your work is saved, so if you have to reformat it wont affect you, and you wont risk doing any damage to the partition/mbr/accidentally formatting during fiddling (sounds silly but I've seen people do it...quite funny from an onlookers perspective though!).
It's more than likely bios related, i had the same problem with Windows 7 and a ASUS P5WDH Deluxe running 4x1GB of ram, i fully tested the ram, even left memtest running for four days with no errors at all, but it still locked up in Win 7, i tested everything again and again, in the end i give up and purchased a new motherboard, problem solved.
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