It should switch over pretty quick as you're already being paid for export by Octopus.
- I set my battery to charge between 2 and 5am, which takes me to about 85% SOC
- After 5am house runs off the battery until solar kicks
- At around 98% battery charging slows and export starts
- Between 16:00 and 19:00 I discharge the battery to no less than 65%
- Battery will then see me through to the 2am charging slot.
Once the second battery is on-line which will give me 29kWh of storage, I'll double the charge rate from the grid, and decrease the minimum SOC probably to about 50% as I'd like to keep some in reserve just in case of a power cut.
At the moment I draw 15kWh from the grid every day, and need to export 12 at the day rate to have zero electric bill for the day, so far I've done much better than that.