William said:http://jchemed.chem.wisc.edu/JCeSoft/CCA/CCA3/MAIN/CLPR/PAGE1.HTM
Granted it needs to be lit in air first, but it is oxidising, read burning/combusting pretty well in chlorine.
You are talking about free radical substitution under UV light yes?
Edit: Just noticed you are a professional scientist, I am probably just digging myself a big grave here.
hmmm, i'm not sure if this could be defined as burning - its certainly oxidising and the chlorine is doing exactly the same job as oxygen - is this 'burning'? - i'm not sure.
i am surprised that methane actually burns in chlorine - chlorine and compounds containing chlorine are pretty good at puting out flames - its the chlorine that quenches and stops the radical processess that occur in burning.
flame retardent materials contain chlorine and similar elements to stop themselves burning.