Soldato
When Starliner is released from the booster, it’s not in a stable orbit. If the thrusters fail to fire, it’ll passively re-enter the atmosphere of its own accord. I don’t know what happens if they all fail halfway through the circularisation burn but seeing as the ISS still orbits inside the atmosphere and has to boost itself back up on a regular basis it would eventually do a full re-entry. I’ve no idea how long that would take though.
NASA will have thought of this though - there were plans for all stages of engine failure in the Space Shuttle ascent profile, and runways around the world it could land on. The Apollo capsule had multiple ways to be separated from the lander when it left the moon, and the engine was a hypergolic one which needed no ignition system to keep it as simple as possible.
No-one is YOLOing space…
The safety measures, all the variables factored in, the relability, the backup systems, it's mind boggling to think of how many things are put in place for these missions.