Why does the PCIe have two heads on it? I can see the one that's in the machine is the same, and both heads are plugged in to the GPU. Can't even see where I'd stick this new one. There's definitely space on the PSU where you've outlined.
Ok did some reading, I'll take the daisy chain out and put the second cable in. Turning off and will report back. Thanks for your help thus far, gentlemen.
Some cards will be fine with the 2x8 pin on one cable, but a Vega 64 can consume up to ~300W, with your specific card it would not be unusual to see closer to 330W in stock form at full load.
The PCI Express slot itself can provide up to 75W. The spec for a 6 pin PCIe cable is 75W, the spec for an 8 pin is 150W. In practice many PSU's are happy to deliver more than that down a single PCIe cable but if we assume your card wants to use ~330W at maximum load, with one cable you're asking it to supply over 250W down a single PCIe cable - around 70% over spec.