I remember as a kid my parents using that reflector foil behind the rads as the heating struggled to keep the house to a modern temperature. The house had background level CH installed.
It also had large metal single glazed windows. Lovely for light, terrible for heating.
My recollection was that it was very very difficult to keep the foam stuck to the wall (it was very thin sheets of metallic covered foam but it may have changed since)
Its probably far easier if you have the rads off the wall so you can glue the whole surface. From memory if you tried to apply it in place you could only stick the edges, and once one started to peel (as the glue gave out) then it eventually ended up partly leaning against the rad itself.