Man of Honour
I'm physically sick if I eat too early. So I always eat after my commute. I read that it's great for increasing your metabolism rate, as long as you don't over do it and eat soon after exercise.
If you're going to be exercising on an empty stomach you may want to look into BCAA supplementation to reduce possible LBM catabolism from your riding. It won't negatively impact the fat burning improvements you'll see from fasted exercise.