ok so couple days later and have to say the S5 is a big refinement over the S3, and the S3 was already very good for sound, just had various technical quirks/issues that I mentioned before. All of those (well all but maybe 1 or 2) have been resolved and the ones that remain seem to be engineering limitations or design choices.
The plastic quality is improved too.
The soundstage is wider than the S3, these give a greater sense of open air which is strange at first since they're closed back. I wondered how the planars are venting air given this but noticed vents on top of each cup that hide under the headband arm bit:
They're over £100 more expensive than the S3 though, so whether they are worth the price will be user preference. Wired mode sounds the same as wireless now (LDAC/aptX-HD) and you can use them wired via USB-C now too so 3 methods of input, dual-device pairing via BT and now has custom EQ control too which seems to remember across all inputs. The pad fit and finish has been revised too:
Think these are a keeper for closed back listening