That not how IOG slots work, if you were on that tariff you'd mostly get off-peak pricing unless you were always doing it between week days at 16:30 and 18:00 when you might have to pay the normal rate, rather than 7p.Now I love the idea of an EV as someone who does 100 miles per day when I work but sadly the charging schedules when I would get home and then need to come off charge would mean I don't get the cheaper costs and would need to charge probably 50% every time.
Also 100 miles at 3.5mpkWh is only 28kWh, so 4 hours charging.
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